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Legal divorce - from ANYWHERE - has absolutely no bearing on the Marital Bond forged in Holy Sacrament.
Oh, your friend could file for a legal divorce, sure. While the state will recognize him (and his ex) as no longer married, in the Eyes of God he and his ex are still married.
What your friend needs is an annulment from the Catholic Church. And, even if he goes for one, there's no guarantee he'll get it. You see, annulment is NOT a 'divorce' by the Church. An annulment is a declaration by the Church that, for a reason that still has yet to be determined (if there is even a reason at all) the marriage was null and void to begin with. Hence, there never was a valid marital bond.
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