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Magically speaking, I've never heard of scorpion powder. Just Scorpio powder (used in zodiac related magic) which is made mainly from herbs, and crab shell powder, made from exactly what it sounds like.
However, I have heard of scorpion powder used in some Chinese medicine. It's made, surprise, from powdered scorpions; and I can imagine it would be useful in certain types of spells. It's called Quan Xie in Chinese. You can buy some here: http://maxnature.stores.yahoo.net/quxiexpoma.html
If you don't need to have edible-quality powder, also, you could perhaps contact a local pet shop and, if you're too soft-hearted to just kill them yourself, ask them if they could give you any scorpions that pass on while in their care.
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